Let's call the apogee radius [MATH]r_a[/MATH]; and the perigee radius [MATH]r_p[/MATH]. (Note that this are 'radii' not 'altitudes'. To convert to altitudes you have to subtract the radius of the Earth.
Now, if we assume that orbits are elliptical, we can say that the speed at perigee is:
[MATH]v_p = \sqrt{\frac{r_a (2 \, \mu )}{r_p \left(r_a+r_p\right)}}[/MATH]
and the speed at apogee is:
[MATH]v_a = \sqrt{\frac{r_p (2 \, \mu )}{r_a \left(r_a+r_p\right)}}[/MATH]
where [MATH]\mu[/MATH] is the gravitational constant for Earth (398600.4418 km^3 s^-2)
Now, these equations are always true for elliptical orbits. In particular, they are true if you are in a circular orbit with orbital radius, [MATH]r_a[/MATH]. In this, case
[MATH]v_a = v_p = v_c = \sqrt{\frac{\mu }{r_a}}[/MATH]
So, the delta-V required to convert your circular orbit to an elliptical one is:
[MATH]v_c - v_a = \sqrt{\frac{r_p (2 \, \mu )}{r_a \left(r_a+r_p\right)}} - \sqrt{\frac{\mu }{r_a}} [/MATH]
(N.B.. to be consistent with units, it is easiest to work in 'km' and 'seconds'. So, this expression will calculate a delta-V in km/s. To convert to m/s, multiply by 1000.
Also note that the number should be negative - indicating a retrograde burn - since you are lowering one side of your orbit)