I've never used Hypothetic Delta-V on aerobrakeMFD, but I believe it's used to help plan an Aerocapture maneuver, and not used for a re-entry.
As for Basesync, it's actually pretty easy to use once you know how to set it up. Press <TGT>, and type in the name of the base. If you're not sure the exact name of a base, use "Object Info" (found in the main (F4) menu)). It's not case sensitive, don't worry about capitalizing. Press <MOD> to enter "closest approach" mode. Press <E/D> to get into "Direct" mode.
At the bottom, one of the lines will be in white. That's the closest pass. It may change after a few orbits if a closer pass is coming. You can "force" Basesync to use a sooner orbit by pressing <NUM> and entering in the number of orbits you want to consider.
If the closest approach is over 100k, I like to "prepare" by doing a plane adjustment a couple orbits before re-entry, especially if I'm in a low (200k) orbit, but you don't have to. Don't bother getting it closer than 50k, things change a little when you perform the de-orbit burn.
Basesync won't count down to a node until the last node (after the de-orbit burn) so if you want to do a prep burn, check the Tn counter. If it's a negative number, use the opposite of the direction the PlC shows. In other words, if PlC shows a plus sign, you'll need to burn anti normal (Normal - ). This is only for burns before the last node. Since you won't get a TN countdown, just burn at the grey line (they should be 90 degrees from the target, if not check to see that you're in "Direct" mode, not "Equatorial".)
When you are on the last orbit, perform your de-orbit burn when on the opposite side of the planet. You can use MapMFD and burn when the distance starts shrinking, or just "eyeball" it using Basesync's display.
Basesync won't start the TN countdown until about one minute to the node, so if the TN number is negative, orient opposite the PlC sign. When you get to the last node (90 degrees before touchdown) burn to reduce the closest approach distance. For Canaveral, I like to head 20km south of the base to provide room for runway alignment. After that last alignment burn, orient for re-entry as normal.